Tishreen University Journal -Basic Sciences Series https://journal.tishreen.edu.sy/index.php/bassnc <p>Print ISSN:2079-3057 , Online ISSN: 2663-4252</p> en-US <p><strong>The authors retain the copyright and grant the right to publish in the magazine for the first time with the transfer of the commercial right to the <a href="http://journal.tishreen.edu.sy/index.php/humlitr">Tishreen University Journal -Basic Sciences Series </a></strong></p> <p><strong> Under a CC BY- NC-SA 04 license that allows others to share the work with of the work's authorship and initial publication in this journal. Authors can use a copy of their articles in their scientific activity, and on their scientific websites, provided that the place of publication is indicted in <a href="http://journal.tishreen.edu.sy/index.php/humlitr">Tishreen University Journal -Basic Sciences Series . </a> The Readers have the right to send, print and subscribe to the initial version of the article, and the title of <a href="http://journal.tishreen.edu.sy/index.php/humlitr">Tishreen University Journal -Basic Sciences Series </a> Publisher</strong></p> <p> </p> <p><strong>journal uses a CC BY-NC-SA license which mean</strong></p> <p>You are free to:</p> <div id="deed-rights" class="row" dir="ltr" style="text-align: left;"> <div class="col-sm-offset-2 col-sm-8"> <ul class="license-properties"> <li class="license share"><strong>Share</strong> — copy and redistribute the material in any medium or format</li> <li class="license remix"><strong>Adapt</strong> — remix, transform, and build upon the material</li> <li class="license remix"> </li> <li class="license remix">The licensor cannot revoke these freedoms as long as you follow the license terms.</li> </ul> </div> </div> <p><strong> </strong></p> <ul> <li><strong>Attribution</strong> — You must give <a href="https://creativecommons.org/licenses/by-nc-sa/4.0/">appropriate credit</a>, provide a link to the license, and <a href="https://creativecommons.org/licenses/by-nc-sa/4.0/">indicate if changes were made</a>. You may do so in any reasonable manner, but not in any way that suggests the licensor endorses you or your use.</li> <li><strong>NonCommercial</strong> — You may not use the material for <a href="https://creativecommons.org/licenses/by-nc-sa/4.0/">commercial purposes</a>.</li> <li><strong>ShareAlike</strong> — If you remix, transform, or build upon the material, you must distribute your contributions under the <a href="https://creativecommons.org/licenses/by-nc-sa/4.0/">same license</a> as the original.</li> </ul> <ul> <li><strong>No additional restrictions</strong> — You may not apply legal terms or <a href="https://creativecommons.org/licenses/by-nc-sa/4.0/">technological measures</a> that legally restrict others from doing anything the license permits.</li> </ul> tishreenjournal.basic@tishreen.edu.sy (Cheif Editor) tishreen.university.journal@tishreen.edu.sy (Dr. Amir Darwish TFIHA) Tue, 23 Apr 2024 05:38:28 +0000 OJS 3.2.1.4 http://blogs.law.harvard.edu/tech/rss 60 Inclusion properties of the generalized homogeneous Herz-Morrey spaces https://journal.tishreen.edu.sy/index.php/bassnc/article/view/16822 <p>In this paper, we study a problem at functional analysis, it is the inclusion of functional spaces, in the beginning we defined the generalized homogeneous Herz - Morrey space&nbsp;, which is a generalization of the homogeneous Herz- Morrey space, then we studied some of its basic properties, where we proved that it is linear, normed and complete space, then we studied its inclusion properties for different cases of the parameters &nbsp;, then we studied the inclusion between the generalized homogeneous Herz- Morrey space and the weak generalized homogeneous Herz – Morrey space, finally we studied the inclusion between the weak generalized homogeneous Herz – Morrey space.</p> Ali Jasser, Mohammad Ali, Hassan Baddour Copyright (c) 2024 https://creativecommons.org/licenses/by-nc-sa/4.0 https://journal.tishreen.edu.sy/index.php/bassnc/article/view/16822 Tue, 23 Apr 2024 00:00:00 +0000 Studying effect of Magnesium and Aluminum ions on structural properties of M- type Barium Hexaferrite https://journal.tishreen.edu.sy/index.php/bassnc/article/view/16667 <p>It was prepared ferrite hexagonal BaFe<sub>12</sub>O<sub>19</sub> pure and ferrite substitutes BaFe<sub>12-2x</sub>Mg<sub>x</sub>Al<sub>x</sub>O<sub>19</sub> with (x=0,0.5,1,2) using ceramic method .It was sintered BaFe<sub>12</sub>O<sub>19</sub> at 1150°c for two hours .The structural characterization of the composites are investigated by x_ray diffraction device.The results obtained using XRD technology revealed the formation of the hexa-ferrite M-type hexagon with average crystal lattice constants (a=5.871,c=23,119)A°,it was found the replacement rate increased ,peak shift occurs at (114) plane to the large 2θ angle.The distance between the crystal planes d for undoped samples (2.620_2.621)A°,after it doped with aluminium and magnesium oxides decreased (2.615_2.611)A°.After sample was sintered and the sintering process causes the increasing of intensity,but decreases the FWHM value,it shows that sintering process influences the grain growth of barium hexaferrite crystals from 34.291nm to 39.902nm and it was noticed when ferrite substitutes increase the values of the crystal lattice constants decrease.</p> Zeina Jamea, Badr AL-aaraj , Sallamah abuo alshamlat Copyright (c) 2024 https://creativecommons.org/licenses/by-nc-sa/4.0 https://journal.tishreen.edu.sy/index.php/bassnc/article/view/16667 Tue, 23 Apr 2024 00:00:00 +0000 Some characterization of glauconite in Syrian coastal phosphate https://journal.tishreen.edu.sy/index.php/bassnc/article/view/16603 <p>The aim of the present study is to characterize the glauconite grains associated with the coastal chain phosphate that distinguish them from Palmyra phosphate, and to compare them between the three sites where it is spread: Ain al-Tineh, Ain Lillon (south of the Haffa area), and Qalaat al-Muhalaba (north of Qardaha.</p> <p>To achieve the objective of the study, a group of samples were collected from the study sites and microscopic thin sections were prepared, that were studied with polarizing microscopy in the laboratories of the Department of Geology at the Faculty of Science, Tishreen University. The shape and color of the glauconite grains were compared at the three sites. The potassium ratios were compared between the studied sites, which was analyzed in the laboratories of the Atomic Energy Commission – Damascus.</p> <p>The sedimentary medium in the coastal phosphate environment was suitable for the living of microbes and bacteria, working to stabilize the trivalent iron, aluminum and magnesium forming the characteristic green slurry of these grains in the first stage, then the microbes work to introduce potassium into the crystalline structure of metals and organic matter.</p> Ahlam Ibrahim Copyright (c) 2024 https://creativecommons.org/licenses/by-nc-sa/4.0 https://journal.tishreen.edu.sy/index.php/bassnc/article/view/16603 Tue, 23 Apr 2024 00:00:00 +0000 Sedimentalogical Evolution of the northern Baer-Bassit during upper Cretaceous https://journal.tishreen.edu.sy/index.php/bassnc/article/view/16225 <p>The sedimentological study of five geological sections in the Upper Cretaceous deposits, exposed in northern Al-Baer-Basit which located beneath the ophiolitic cover, revealed the presence of four intermediate sedimentary sequences in the Turonian-Senonian deposits: regressive, transgressive-neutral, regressive-regressive and transgressive. These sedimentary sequences are related to sea level changes and the uplift of the bottom of the sedimentary basin because of ophiolitic obduction in northwestern of Syria. During the Turonian-Senonian, the sedimentation environments ranged from subtidal in the open sea to supratidal to even continental environments, in which sediments are rich in detrital were dominant</p> Abdulkarim AlAbdalla, Samer AL-BUB Copyright (c) 2024 https://creativecommons.org/licenses/by-nc-sa/4.0 https://journal.tishreen.edu.sy/index.php/bassnc/article/view/16225 Tue, 23 Apr 2024 00:00:00 +0000 Synthesis two crystalline compoundsSr2-xSmxCoO4 belonging to the RUDDLESDEN-POPPER series by partial sustention of strontium (Sr) with samarium (Sm) and study their crystal structure and some physical properties. https://journal.tishreen.edu.sy/index.php/bassnc/article/view/16215 <p>The oxides of Sr2-xSmxCoO4 (X=1 ,1.25) were Synthesised using the ceramic method and the effect of partial sustention of Sr with Sm in crystal lattice of compound Sr2CoO4has been studied. The phases and structures were studied using powder x-ray diffraction and HRTEM(High Resolution Transmission Electron Microscopy). The compounds found to be of the 214 crystal system at n=1 of the tetragonal system of the I4/mmm space group of K2NiF4 crystal model. It was observed that the value of the parameter c decreased while the value of the parameters a,b and the volume of the cell of crystal structure increased with the increasing of the value of X. Magnetic properties were measured and curie temperature was observed between 160-200 k for sample of x=1, while antiferromagnetic behaviour was observed at 35 K for sample X = 1.25.</p> manar hassan Copyright (c) 2024 https://creativecommons.org/licenses/by-nc-sa/4.0 https://journal.tishreen.edu.sy/index.php/bassnc/article/view/16215 Fri, 12 Apr 2024 00:00:00 +0000 The influence of alumina ratio on the properties of the Al-MCM-41 mesoporous structure https://journal.tishreen.edu.sy/index.php/bassnc/article/view/16194 <p>Three samples of the mesoporous structure Al-MCM-41 were prepared by hydrothermal treatment method using silica and a structure-oriented agent (CTRB), with a molar ratio of Silica:CTAB is 1: 0.5 with a chang in the aluminum &nbsp;ratio so that it was (0-10-20)% . The results showed that the changing of alumina ratio was affected notely on the prepared structures. Whereas, the specific surface area was decreased from 874.0 to 329.7 and 88.9 m<sup>2</sup>/g when the alumina ratio 0,10,and 20% respectively, and the total pore volume decreased from 0.63&nbsp; to 0.35 and 0.24 ml/g &nbsp;according to alumina ratio 0,10,and 20% respectively. The pore radius increased from 14.4&nbsp; to 21.5 and 53.7 ºA &nbsp;for alumina ratio 0,10,and 20%, while . The pore volume distribution was decreased from 28 for alumina ratio 0% to 12% for both alumina ratio 10 and 20%. While a convergence was observed in the spectra of XRD diffraction, and infrared spectra (FT-IR) with a slight difference as the shift of the peak or disappearance of the other with the increase in the molar ratio of aluminum..</p> Ayham Ghandour, Ibrahem Raheb, Hussam Alrakad Copyright (c) 2024 https://creativecommons.org/licenses/by-nc-sa/4.0 https://journal.tishreen.edu.sy/index.php/bassnc/article/view/16194 Fri, 12 Apr 2024 00:00:00 +0000 The Effect of Harmonic Distortion in Capacitive and Inductive Loads on the Performance of Electrical Grids in Huge Projects (FADEN Spectrum Phenomenon - an example) https://journal.tishreen.edu.sy/index.php/bassnc/article/view/16058 <p><strong>&nbsp;</strong></p> <p><strong>&nbsp;</strong></p> <p>This research deals with the study, analysis and treatment of a strange phenomenon that suddenly appeared during the installation of a huge screen belonging to FADEN Spectrum Company on one of the huge towers in the city of Al-Khobar in the Kingdom of Saudi Arabia with area of 2000 m2, consisting of 2000 cabins and feeding 2000 cells, each cell having an area of 1 m2.</p> <p>&nbsp;</p> <p>This phenomenon includes two things: The first is the appearance of an annoying noise emanating from the main feed box (MDB), and the noise increases exponentially with the increase in lighting intensity to become a noise of 90 dB at 60% illumination and 155 dB at 100% illumination.</p> <p>&nbsp;</p> <p>As for the second, most surprising thing, it is the cables getting hot at a point that exiting from the panel ceiling only, where the temperature reached #83C, noting that the cables before and after this point were not affected by this temperature at all, so that temperature was #28C before the entry point, and the same temperature after the exit point, while the iron metal of the panel ceiling was clearly affected, that also recorded #83C.</p> hazar shtat Copyright (c) 2023 https://creativecommons.org/licenses/by-nc-sa/4.0 https://journal.tishreen.edu.sy/index.php/bassnc/article/view/16058 Sat, 18 Nov 2023 00:00:00 +0000 Preparation and study of the common oxide system Al2O3/Fe2O3 and the effect of the directing agent (polyethylene glycol) on the properties of the tissue structure https://journal.tishreen.edu.sy/index.php/bassnc/article/view/16018 <p> In this work, the mixed oxide was prepared in reactive proportions by hydrothermal method. The samples have been treated at temperature 110 <sup>o</sup>C for 7 hours. The effect of the amount of directing agent (polyethylene glycol) on the specific surface area value of the prepared samples was studied. The highest value of the specific surface area was 378.0 m<sup>2</sup>/g at molar ratio without directing agent. when prepared by the dry method at a ratio of without directing agent using ammonium bicarbonate as a precipitating agent.</p> <p>Using amount of directing agent(g) the specific surface area decreased to 132.9 m2/g for the sample ,p(0.10g). when The amount of directing agent was increased the size of the mesoporous was increased, and the specific surface area ( increased to maximum 325.9 m<sup>2</sup>/g for the sample ,p(0.4g(</p> duaa shahin, Husam Al-dien Kawass, Samira Suliman Copyright (c) 2024 https://creativecommons.org/licenses/by-nc-sa/4.0 https://journal.tishreen.edu.sy/index.php/bassnc/article/view/16018 Tue, 23 Apr 2024 00:00:00 +0000 A study of the effect of Mueller matrices and Stokes vectors on calculating the polarization parameters of the linear, circular, and elliptical light field. https://journal.tishreen.edu.sy/index.php/bassnc/article/view/16011 <p>In this research, the polarization equation was extracted, the Stokes vectors were defined, and we performed the appropriate transformations of the optical field components in a form consistent with the Mueller matrices for polarization. We determined how to calculate the components of the matrix, which in turn determine the state and type of polarization. We demonstrated the importance of this study in calculating and knowing the optical properties such as photo activity and refractive index. The theoretical results were compared with the available and recent experimental results</p> Imad Abdullah, Ghayath Yassin, Mahmoud Ahmed Copyright (c) 2024 https://creativecommons.org/licenses/by-nc-sa/4.0 https://journal.tishreen.edu.sy/index.php/bassnc/article/view/16011 Tue, 23 Apr 2024 00:00:00 +0000 Conversion of Apricot Kernel Oil into Biodiesel Using Alkaline Catalysts https://journal.tishreen.edu.sy/index.php/bassnc/article/view/15963 <p>Biodiesel is a clean - burning alternative fuel source that can be produced from animal fats, vegetable oils, and algae oil. This research deals with the production of biodiesel from apricot seeds oil, which is a rich source of oil. The oil was extracted from apricot seeds by maceration using n-hexane as a solvent. Biodiesel was prepared by the alkaline catalyzed transesterification method, and the reaction yield reached 86.3 % at the reaction conditions: molar ratio of oil: methanol ( 1:6 mol/mol), the amount of catalyst (0.5 wt % of the weight of the oil), reaction temperature 65 °C over 90 minutes. the physical and chemical properties of the prepared biodiesel were studied , and they confirmed the American (ASTM) and European (EN) Standards. In addition, The combustion test of the prepared biodiesel was carried out and the results were discussed.</p> Baraa Siyo Copyright (c) 2024 https://creativecommons.org/licenses/by-nc-sa/4.0 https://journal.tishreen.edu.sy/index.php/bassnc/article/view/15963 Fri, 12 Apr 2024 00:00:00 +0000 An Investigation In The Inclucion Theorem Which Related To Lorentz Spaces https://journal.tishreen.edu.sy/index.php/bassnc/article/view/15947 <p>In this paper, we studied a problem at functional analysis, it is the inclusion of function spaces, especially we studied the inclusion between Lorentz space type (r,p,q), In the beginning, we introduced this space and then, we studied some of its basic properties where we proved that it is non-empty, linear, quasi-normed and complete space, then we proved the inclusion of this space for different cases of the parameters, First for1≤q_1≤q_2&lt;∞ , then for 0≤r_2≤r_1&lt;∞ , <br>after that for 0≤r_2≤r_1&lt;∞ &amp; و1≤q_1≤q_2&lt;∞ at the same time. <br>In addition to some other inclusion cases. <br>Then, we proved one of the cases of inclusion between these spaces and bounded stummel modulus classes type (r, q,α).</p> ali jasser, Mohamad Ali, Hassan Baddour Copyright (c) 2023 https://creativecommons.org/licenses/by-nc-sa/4.0 https://journal.tishreen.edu.sy/index.php/bassnc/article/view/15947 Sun, 19 Nov 2023 00:00:00 +0000 Estimation of the Peak Discharge in the Arab River basin in Lattakia, Syria by the modified experimental Talbot method TMT https://journal.tishreen.edu.sy/index.php/bassnc/article/view/15780 <p>The lack of continuous hydrological records is one of the biggest challenges&nbsp; in managing surface basin water resources, especially when studying floods and the water installations. Therefore, many hydrological researchers applied experimental equations&nbsp; to estimate the peak flow values, as a basic parameter that plays a key role when establishing water projects in the absence of hydrological measurement stations. The modified experimental Talbot method TMT is one of the most famous of these equations, which was applied in this study to estimate the peak flow values ​​in the Arab River basin using GIS software and building purpose maps (geomorphological coefficient, slope, shape, drainage …) and processed to obtain a map of the distribution of the estimated peak flow values, It was found that it ranged on average between (2.5 m<sup>3</sup>/s) with a return period (5 years) and a maximum of (30 m<sup>3</sup>/s) with a return period (100 years), The study also showed that the higher values ​​of the estimated flow peak are concentrated in the recharge area in the Arab River Basin, while the lower values ​​are concentrated in the drainage area, which reduces the possibility of flooding.</p> Dareen Bourjiah Copyright (c) 2024 https://creativecommons.org/licenses/by-nc-sa/4.0 https://journal.tishreen.edu.sy/index.php/bassnc/article/view/15780 Fri, 12 Apr 2024 00:00:00 +0000 Effect of the hydrothermal treatment and amount of structure directing agent on the surface properties for SBA-15 mesostructure https://journal.tishreen.edu.sy/index.php/bassnc/article/view/15637 <p>&nbsp;&nbsp;&nbsp; Six samples of SBA-15 mesostructure were prepared. Process was proceeded with constant amount of TEOS, at different temperatures (70,100 and 130 Cº) using different amounts of P123 as structure directing agent (SDA).</p> <p>Results showed that both, the temperature of the hydrothermal treatment and the amount of (SDA) clearly affect on isothermal adsorption curves and the all pore structure factors.&nbsp; When the mass of SDA was 23 m.mol at different temperature &nbsp;&nbsp;&nbsp;(70,100,130 Cº) the specific surface area was 640,734 and 382 m<sup>2</sup>/g respectively.</p> <p>Where at constant temperature 100 Cº and different mass of SDA (23, 46, 69 m.mol ) the surface area was 734,852,832 m<sup>2</sup>/g respectively .The distribution of pore volume also was changed.</p> Reem Almorshidi, Ibrahim Raheb, Husam Al_din Kawasse Copyright (c) 2023 https://creativecommons.org/licenses/by-nc-sa/4.0 https://journal.tishreen.edu.sy/index.php/bassnc/article/view/15637 Sun, 19 Nov 2023 00:00:00 +0000 Extraction of lanthanum (III) ion from aqueous solutions using Formazan reagent by liquid-liquid method https://journal.tishreen.edu.sy/index.php/bassnc/article/view/15624 <p>The current study included a liquid-liquid extraction of the trivalent lanthanum ion by means of the reagent ((3,1-diphenyl-5-(p-nitrophenyl)formazane)), and the effect of various factors was studied on the percentage of extraction and the extraction coefficient, including the pH of the medium. , Mixing the two phases, the concentration of the studied ion, and also the effect of the presence of some competitive positive ions, and the effect of the extraction process in batches, in addition to studying the effect of the ratio of the organic phase to the aqueous phase.</p> <p>The results of this research showed that the best equilibrium time was at 90 minutes, and the best PH degree was at PH = 5. As for the extraction process in batches, the results showed that it was not very effective, so it was better to extract in one batch to save effort and time.</p> <p>The value of the distribution coefficient and the transition ratio increased with the increase in the concentration of the lanthanium ion in the aqueous phase, and this behavior was expected due to the continuous interaction between the ions and the formazan. As for the effect of the presence of some positive ions competing for the lanthanium ion, the greatest effect was the triple chromium ion (Cr<sup>3+</sup>).</p> <p>In general, and through the results of the research, it is noted that the formazan reagent can be used effectively in the process of extracting ternary lanthanum from aqueous solutions, and later used in extracting it from real samples such as solutions resulting from phosphates and phosphogypsum</p> Ali Mohamed , Mohammad Ghafar, Maher Dais Copyright (c) 2023 https://creativecommons.org/licenses/by-nc-sa/4.0 https://journal.tishreen.edu.sy/index.php/bassnc/article/view/15624 Sun, 19 Nov 2023 00:00:00 +0000 Preparation and Characterization of high surface area material from natural Syrian zeolite TS-7 https://journal.tishreen.edu.sy/index.php/bassnc/article/view/15547 <p>The porous silica Si- TS-7 has been prepared from Syrian natural zeolite TS-7. Natural zeolite was treated with hydrochloric acid 10%wt for 24h at 20<sup>o</sup>C. The product was filtered to remove the precipitate. Filtrate has been used to produce solid base in previous work. The precipitate has washed with distilled water and dried at 110<sup>o</sup>C for 24h and calcined at 500<sup>o</sup>C for 4h. The resulted material Si-TS-7 was characterized by TG-DTA and FTTR, XRD BET methods. The results showed that the Si-TS-7 consist of silica mainly. Textural properties study showed that the adsorption isotherm belongs to type IV according to the classification of Singh and colleagues, which is characterized by the presence of a hysteresis loop that indicates the presence of the phenomenon of capillary condensation and presence of high specific surface area of 412m<sup>2</sup>/g compared to crude zeolite.</p> Hussam Alrakkad Copyright (c) 2023 https://creativecommons.org/licenses/by-nc-sa/4.0 https://journal.tishreen.edu.sy/index.php/bassnc/article/view/15547 Tue, 12 Sep 2023 00:00:00 +0000 Determination of the concentrations of some organophosphorus pesticides in the muscle tissue of exotic fish (Siganus rivlatus) spread on the beach of Latakia city https://journal.tishreen.edu.sy/index.php/bassnc/article/view/15542 <p>This research focused on determining the concentrations of some organophosphorus pesticides in the muscle tissue of exotic fish (Siganus rivlatus) in five different areas of the coast of Latakia city (northern estuary of the Kabir River, Marfa, Afamia, Sports City and Sakiet Musa) in winter 2023.</p> <p>A significant increase in the total concentrations of organophosphorus pesticides was observed in fact significantly affected by wastewater and agricultural activities, commercial activity at the port site (6895 ± 35.12ng/g), the northern estuary of the Kabir River (3243.71 ± 32.1ng/g), the Apamea site (1161.62±34.67ng/g) and the Sakiet Moussa estuary site (774.41 ± 33.75ng/g) in increasing their concentrations in the muscle tissues of sandy exotic fish compared to the Sports City site (169.75 ± 29.38ng/g) relatively far from sources Direct pollution.</p> <p>The results showed a high values of the standard deviation coefficient between the fish of each site on the one hand, and between the fish of different sites on the other hand, which can be attributed to the effect of both the feeding pattern (herbivorous fish), in addition to the different morphological characteristics of the studied fish (height and weight) and the age of the fish in the different concentrations of these pesticides, This was confirmed by the strong correlations between concentrations and the length and weight of the fish studied.</p> <p>The accumulation of organophosphorus pesticides across the food chain in the muscle tissue of the sand exotic fish (<em>Siganus</em> rivlatus) being lipophilic has negative consequences on fish on the one hand, in addition to the negative effects on the top of the pyramid in this food chain, which is human, which leads to serious diseases and significant negative effects on it.</p> Hussam Alddin Laika Copyright (c) 2023 https://creativecommons.org/licenses/by-nc-sa/4.0 https://journal.tishreen.edu.sy/index.php/bassnc/article/view/15542 Sat, 18 Nov 2023 00:00:00 +0000 Studing the luminescence and excitation of Calcium Fluoride and matching it with computer. https://journal.tishreen.edu.sy/index.php/bassnc/article/view/15509 <p>Calcium fluoride was prepared using the chemical precipitation method, The absorption spectrum was taken with a methanol dispersion</p> <p>The oscillator strength of the vibrator was calculated for the possible transitions by matching the experimental absorption spectrum with the theoretical spectrum, assuming that the spectral line shape is Gaussian and the number of spectral lines of the absorption spectrum is seven lines, a decoupling of the experimental absorption curve was made, and then the wavelengths corresponding to the most probable transitions were found.</p> <p>The emission spectrum of the prepared sample was taken at an excitation length of 300 nm and an emission peak was observed at the wavelength of 400 nm.</p> Nawaf Ismael, Burhan Dalati, Mahmoud Ahmad Copyright (c) 2023 https://creativecommons.org/licenses/by-nc-sa/4.0 https://journal.tishreen.edu.sy/index.php/bassnc/article/view/15509 Sun, 19 Nov 2023 00:00:00 +0000 Studying the Nature of Recent Marine Sediments on the Accumulation of Cadmium and Lead in Latakia and Baniyas Shore https://journal.tishreen.edu.sy/index.php/bassnc/article/view/15344 <p>This research based on the determination of some trace heavy metals (Lead (Pb), cadmium (Cd)), in different types of recent marine sediments and studying their grained isolation along different zones of Latakia and Baniyas shore area during summer period of 2022 using (Atomic Absorption Spectrometry: AAS).</p> <p>Moreover this research aimed to determine the correlation between The following factors, quality and nature of the sediment also the effect of the grained particle diameter on the change of these concentrations. The results indicate that there is a significant correlation between the change in the concentrations of the studied metal elements (lead (Pb) and cadmium (Cd)) and the nature and quality of the sediment, where it was observed almost complete dominance of sands, moderate isolation, and with a very negative slope in the shore of Latakia city, which indicates relatively moderate energy conditions compared to the predominance of gravel sands, with poor sorting, excessive and with a very negative slope, which indicates high energy conditions in Baniyas beach.</p> bdoor khret, Samer Ghadeer, Hussam Eddin Laika Copyright (c) 2024 https://creativecommons.org/licenses/by-nc-sa/4.0 https://journal.tishreen.edu.sy/index.php/bassnc/article/view/15344 Tue, 23 Apr 2024 00:00:00 +0000 Study of the Effect of Various Human Activities on the Distribution of some Organophosphorus Pesticides in the Marine Waters of the Coast of Lattakia ity https://journal.tishreen.edu.sy/index.php/bassnc/article/view/15321 <p>This research focused on the determination of the concentrations of some organophosphorus pesticides in five different areas of the coast of Latakia city (northern estuary of Nahr al-Kabir, Al-Marfa, Afamia, Sports City and Sakiet Moussa) using gas chromatography technology related to spectrometry gaschromatography/MS (GC/MS).</p> <p>The results showed that the total concentrations of organophosphorus pesticides were significantly higher in the marine waters of the port site (111.115μg/l) and the northern mouth of the Kabir River (39.899μg/l), with the lowest values recorded at the Sports City site (1.158μg/l). Diazinon recorded the highest values in the harbor area (71.802μg/l), and Dimethoat in the northern estuary of the Kabir (26.592μg/l).</p> <p>It was noted that the Sports City area is the least studied area of concentrations of these pollutants compared to various other studied sites, while the diversity is great in the number of vehicles.</p> Hussam eddin Laika Copyright (c) 2023 https://creativecommons.org/licenses/by-nc-sa/4.0 https://journal.tishreen.edu.sy/index.php/bassnc/article/view/15321 Tue, 12 Sep 2023 00:00:00 +0000 Study the effect of temperature and shear stresses on flow behavior Polylactic acid - polystyrene (PLA/PS) molten mixture https://journal.tishreen.edu.sy/index.php/bassnc/article/view/15319 <p>In this research, we have studied the rheological properties of samples of PLA / PS mixtures under the influence of high shear stress and different temperatures, where mixtures were prepared in proportions ranging from 10% to 100%. The mixtures (mixtures) were prepared in preparation for the tests in the viscometer Then study the viscous properties by determining the viscosity and viscous activation energy (E) at constant shear stress, constant shear rate and through Newton's index (n).</p> <p>&nbsp;</p> <p>The real viscosity transformations were also studied in terms of the inverse of temperature to determine the activation energy at constant shear stresses and constant shear speed, as the activation energy is useful in determining the sensitivity of the polymer's viscosity to temperature change.</p> <p>The elastic properties of the studied mixtures were also studied using Barus technology, and it was found that the rate of swelling increases with the increase in shear stress, and it was found that there is no significant effect on the swelling coefficient B.</p> Hala Al-Kateb, Hassan Wassouf, Fawaz Al-Dairi Copyright (c) 2024 https://creativecommons.org/licenses/by-nc-sa/4.0 https://journal.tishreen.edu.sy/index.php/bassnc/article/view/15319 Fri, 12 Apr 2024 00:00:00 +0000 Quantum mechanical investigation of the Mechanism of Nickel-Catalyzed Cycloaddition Reaction of 3-azetidinone with Alkynes https://journal.tishreen.edu.sy/index.php/bassnc/article/view/15263 <p>The reaction mechanism of the 3-azetidinone with nickel-catalyzed alkenes was studied using the function M06-2X with two basis sets: def2-TSVP and LANL2DZ for the nickel atom with two basis sets def2-SVP and 6-31G(d) for the main elements atoms. The computational results indicate that the reaction takes place through two independent pathways, one of which is linked by the coordination of 1-Boc-3-azetidinone on the Ni(0) center to form an intermediate state that includes the Ni–C(O) bond, then the insertion of the alkyne to the Ni–CO bond (pathway 1), As for pathway 2, it is related to the coordination of the 1-Boc-3-azetidinone on the Ni(0) center to form an intermediate state that includes the Ni–C(sp3) bond, and then the insertion of the alkyne to the Ni–C(sp3) bond. <br>Analysis of the global nucleophilic and electrophilic indices of the reagents indicates that the nickel complex shows a strong nucleophilic role, while the compound 3-azetidinone shows an electrophilic role, and that the reaction is polar in its nature. In addition, the local electrophilic and nucleophile indices of the reactants indicate that the nickel atom in the complex is the most nucleophilic center, while the carbon atom C(=O) in the compound 3-azetidinone is the most electrophilic center, and thus, pathway 1 More likely than Pathawy 2. The computational results of our studies are consistent with previous research with the exception that the mechanism proceeds through two independent pathways; That is, there are no common transitional or intermediate states in the two pathways, and this contradicts what was indicated in previous computer studies</p> <p>&nbsp;</p> ahmad sotal, Mohammad Abd Al-Hakim badawi Copyright (c) 2024 https://creativecommons.org/licenses/by-nc-sa/4.0 https://journal.tishreen.edu.sy/index.php/bassnc/article/view/15263 Tue, 23 Apr 2024 00:00:00 +0000 Study of the Antioxidant Activity of Azo Chalcone and Azoflavone Derivatives by DPPH and H2O2 Methods https://journal.tishreen.edu.sy/index.php/bassnc/article/view/15260 <p>Flavonoids have good efficacy as antioxidants due to their ability to scavenge free radicals within cells. The antioxidant activity of azochalcone derivatives (B<sub>1</sub>-B<sub>3</sub>) &nbsp;and azoflavone derivatives (B<sub>4</sub>-B<sub>6</sub>) based on chalcone (<em>2E</em>)-3-[4-(dimethylamino)phenyl]-1-(2-hydroxyphenyl)prop-2-en-1-one was studied by two methods: : Method of radical inhibition of 2,2-diphenyl-1-picrylhydrazyl (DPPH<strong><sup>.</sup></strong>), method of inhibition of hydrogen peroxide (H<sub>2</sub>O<sub>2</sub>) and comparison with the effectiveness of two compounds ascorbic acid and quercetin as known antioxidants. The flavonoid derivatives (B<sub>1</sub> - B<sub>6</sub>) were prepared in the laboratory in our previous study through condensation, cyclization, dialysis and coupling reactions, and the structural structures of the new compounds were determined using spectroscopic methods (<sup>13</sup>C-NMR, <sup>1</sup>H-NMR, FT-IR). The inhibition ability of flavonoids was determined in four different concentrations (250, 500, 750, 1000 ppm) based on the concentrations of the compounds needed to reduce the absorption at 516 nm (DPPH<strong><sup>.</sup></strong>) and 230 nm (H<sub>2</sub>O<sub>2</sub>). The value of IC<sub>50</sub> was estimated based on the curves of change in percentage inhibition percentages in terms of solution concentration. The results showed the effectiveness of compounds (B<sub>1</sub>, B<sub>2</sub>) as antioxidants.</p> Hadi Aqel Khdera, Sawsan Youseff Saad, Aoula Moustapha, Farouk Kandil Copyright (c) 2023 https://creativecommons.org/licenses/by-nc-sa/4.0 https://journal.tishreen.edu.sy/index.php/bassnc/article/view/15260 Tue, 12 Sep 2023 00:00:00 +0000 correlation between mechanical properties of garnet ferrite crystal Dy₃Fe₅O₁₂ with their IR Data https://journal.tishreen.edu.sy/index.php/bassnc/article/view/15203 <p>This research aims to prepare samples of garnet ferrite Dy₃Fe₅O₁₂ doping with Ni – content (x=0.00;0.15; 0.25; 0.35; 0.45; 0.50) using the ceramic method. Then, we used the Nelson Riley method for determining lattice parameter <strong>a</strong> which has an important role to estimate the theoretical X-ray density and the stiffness modulus. In addition, the IR spectra have been taken and their data correlated with the mechanical properties of these samples.</p> ibrahim ali Copyright (c) 2023 https://creativecommons.org/licenses/by-nc-sa/4.0 https://journal.tishreen.edu.sy/index.php/bassnc/article/view/15203 Sat, 18 Nov 2023 00:00:00 +0000 A study of the distribution of polychlorinated biphenyls (PCBs) in the coastal marine waters of Lattakia city https://journal.tishreen.edu.sy/index.php/bassnc/article/view/15174 <p>In this research, the concentrations of some polychlorinated biphenyls (PCBs: Polychlorinated Biphenyls) were determined in the marine coastal waters of the city of Lattakia from the two locations (Southern Corniche area) and (The Sports City area) during the summer and winter seasons of 2022 using gas chromatography - mass spectrometry (GC\MS).</p> <p>The results of the study showed that these studied areas are affected by these pollutants, which indicates that these areas are affected by tourism activities, urban construction, sewage channels for homes and restaurants, or transport through river waters that flow directly into these areas, where the total concentration of PCBs was (Ʃ PCBs) ranges from 22.103 μg/l to 46.553 μg/l.</p> <p>The lowest value of these compounds was in the Sports City area during the winter, when the value was 22.103 μg/l, and the highest was in the Southern Corniche area during the summer, when the value was 46.553 μg/l.</p> <p>This study also showed an increase in the total concentration of polychlorinated biphenyls (Ʃ PCBs) in the studied areas during the summer compared to its concentrations in the winter.</p> Mulham Askar, Ahmad Kara Ali, Ahmad Kara Ali, Hazem Krawi Copyright (c) 2023 https://creativecommons.org/licenses/by-nc-sa/4.0 https://journal.tishreen.edu.sy/index.php/bassnc/article/view/15174 Tue, 26 Sep 2023 00:00:00 +0000 Extraction of some metal ions Residues from burning heavy fuels Used in electric power stations. https://journal.tishreen.edu.sy/index.php/bassnc/article/view/15045 <p>Nickel, vanadium and magnesium ions were extracted from the heavy fuel residues used in electrical power stations and heating furnaces of production units. This extraction was done by organic ester-phosphorous ligands and amputated amines. To separate these ions from the residue, a small laboratory device was designed for separation in two stages: first, base dissolution to dissolve and deposite the vanadium oxide with an ammonized, amputated compound. Second, Sour dissolution of both oxide nickel and oxide vanadium and the extraction of their ions through selective phosphoric compounds, organic soil such as:&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; &nbsp;</p> <p>&nbsp;</p> <p>1 - (C<sub>16</sub>H<sub>14</sub>PSNO<sub>3</sub>) O-(quinolin-8-yl) (o-tolyl) thio-hydrogen phosphate.</p> <p>.(O-(quinolin-8-yl) (o-tolyl) hydrogen phosphate&nbsp; &nbsp;(C<sub>16</sub>H<sub>14</sub>PNO<sub>4</sub>)- 2&nbsp;&nbsp;</p> <p>O-phenyl O-(8-quinolin) thio hydrogen phosphate. &nbsp;&nbsp;3 - (C<sub>15</sub>H<sub>12</sub>PSNO<sub>3</sub>)</p> <p>&nbsp;</p> Moein Nouaman, Faisal Ahmed Copyright (c) 2023 https://creativecommons.org/licenses/by-nc-sa/4.0 https://journal.tishreen.edu.sy/index.php/bassnc/article/view/15045 Sat, 18 Nov 2023 00:00:00 +0000