Synthesis and Characterization of Some New Azo Dyes, Azomethine Dye From New Schiff Bases (2-amino fluorene/p- hydroxyacetophenone) And (2-amino fluorene/p- aminoacetophenone)
Abstract
Aseries of Schiff base and their derivative (2-amino fluorene) have been synthesized by para hydroxy acetophenone was condensed with 2-amino fluorene in DMF (dimethyl form amide) in the presence of conc. HCl acid as catalyst to yield the Schiff bases (1). The Schiff’s base (1) was treated with diazotised p-sulphanilic acid to give Azo Dye compound (2), and The Schiff’s base (1) was treated with benzene diazonium salt solution to give Azo Dye compound (3), The Schiff base (4) was prepared by para amino acetophenone was condensed with 2-amino fluorene in DMF (dimethyl formamide) in the presence of conc. HCl acid as catalyst. Then the reaction of Schiff base (4) with 2-hydroxy-5-methyl-1,3-benzene dicarbox aldehyde to give Azomethine Dye compound (5).
The structures of synthesized compounds has been established on the basis of their spectral (FT-IR, Mass, 1H-NMR, 13C-NMR, elemental analysis) data. TLC confirmed the purity of the compounds.
Downloads
Published
How to Cite
Issue
Section
License
This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.
The authors retain the copyright and grant the right to publish in the magazine for the first time with the transfer of the commercial right to the Tishreen University Journal -Basic Sciences Series
Under a CC BY- NC-SA 04 license that allows others to share the work with of the work's authorship and initial publication in this journal. Authors can use a copy of their articles in their scientific activity, and on their scientific websites, provided that the place of publication is indicted in Tishreen University Journal -Basic Sciences Series . The Readers have the right to send, print and subscribe to the initial version of the article, and the title of Tishreen University Journal -Basic Sciences Series Publisher
journal uses a CC BY-NC-SA license which mean
You are free to:
- Share — copy and redistribute the material in any medium or format
- Adapt — remix, transform, and build upon the material
- The licensor cannot revoke these freedoms as long as you follow the license terms.
- Attribution — You must give appropriate credit, provide a link to the license, and indicate if changes were made. You may do so in any reasonable manner, but not in any way that suggests the licensor endorses you or your use.
- NonCommercial — You may not use the material for commercial purposes.
- ShareAlike — If you remix, transform, or build upon the material, you must distribute your contributions under the same license as the original.
- No additional restrictions — You may not apply legal terms or technological measures that legally restrict others from doing anything the license permits.