دراسة الانتقال الضوئيCo 3p→3d في البلورة TbBaCoO3 بوساطة مطيافية الإصدار الضوئي التجاوبي
Abstract
أنجزت اختبارات الإصدار الضوئي التجاوبي على بلورة البيروفسكايت TbBaCoO3 عند درجة حرارة الغرفة من أجل سطوح مكشوطة حديثاً. استخدمت طاقة بداية التجاوب عند العتبةCo3p→3d لتحديد مساهمة الالكتروناتCo3d في عصابة تكافؤ البلورة. تم تحديد منحنيات توزيع الطاقة EDC المطابقة لعصابة تكافؤ البلورة من أجل طاقة إشعاع hv=60 eV. من أجل طاقة ارتباط 63.2eV وجدت المساهمة الرئيسية لإلكترونات Co3d في القمة الرئيسية عند طاقة7.46 eV تحت سوية فرمي، في حين لوحظت مساهمة إلكترونات Tb4f عند طاقة 12.08eV تحت سوية فرمي. كما بينت النتائج أن كثافة السويات بقرب سوية فرمي تأخذ صفة التهجين Co3d/O2p، وبدون أي مساهمة من Tb4f.
Resonant photoemission of single crystals of the perovskite TbBaCoO3 has been carried out for freshly scraped surfaces. The resonance onset energy at the Co3p→3d threshold is used to explore the contribution of Co3d electrons to the electronic structure of the valence band. The Energy Distribution Curves (EDC) corresponding to the valence band of the crystal were determined for radiation energies hv in the region of hv=60 eV. For 63.2 eV binding energy, the main contribution of Co 3d electrons was found in the main valence band peak located at 7.46 eV below the Fermi level, whereas the contribution of Tb4f electrons was found at energy 12.08 eV below the Fermi level. The results show that the density of states close to the Fermi energy is of Co3d/O2p character, with any Tb4f contribution.
Downloads
Published
How to Cite
Issue
Section
License
This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.
The authors retain the copyright and grant the right to publish in the magazine for the first time with the transfer of the commercial right to the Tishreen University Journal -Basic Sciences Series
Under a CC BY- NC-SA 04 license that allows others to share the work with of the work's authorship and initial publication in this journal. Authors can use a copy of their articles in their scientific activity, and on their scientific websites, provided that the place of publication is indicted in Tishreen University Journal -Basic Sciences Series . The Readers have the right to send, print and subscribe to the initial version of the article, and the title of Tishreen University Journal -Basic Sciences Series Publisher
journal uses a CC BY-NC-SA license which mean
You are free to:
- Share — copy and redistribute the material in any medium or format
- Adapt — remix, transform, and build upon the material
- The licensor cannot revoke these freedoms as long as you follow the license terms.
- Attribution — You must give appropriate credit, provide a link to the license, and indicate if changes were made. You may do so in any reasonable manner, but not in any way that suggests the licensor endorses you or your use.
- NonCommercial — You may not use the material for commercial purposes.
- ShareAlike — If you remix, transform, or build upon the material, you must distribute your contributions under the same license as the original.
- No additional restrictions — You may not apply legal terms or technological measures that legally restrict others from doing anything the license permits.