Preparation and Characterization of solid base Cat.TS-7 from natural Syrian zeolite TS-7

Authors

  • Hussam Alrakkad Tishreen University
  • Ibrahem Raheb Tishreen University

Abstract

Solid base TS-7 has been prepared from Syrian natural zeolite. Natural zeolite was treated with hydrochloric acid 10%wt for 24h at 20oC. The product was filtered to remove the silica precipitate. Ammonium hydroxide solution was added to the filtrate until it forms a gel of dissolved metal hydroxide. A certain amount of cetyl trimethyl ammonium bromide was added, and the product was placed in thermal autoclave, and the system was heated at 135oC for 8h. after the heating process the autoclave was cooled to the room temperature, and the product was filtered and washed with distilled water and dried at 110oC for 24h and calcined at 750oC for 4h. The resulted catalyst Cat.TS-7 was characterized by TG-DTA, FTTR, XRD and TPD methods. The results showed that the Cat.TS-7 consist of two crystalline phases  α-Fe2O3 and ɣ-Al2O3 mainly. The amount of strong basic centers of  Cat.TS-7 was 0.282 m.mol/g. the performance of Cat.TS-7 was tested in the biodiesel reaction and the yield of the reaction was 93.1%.

Downloads

Published

2023-03-27

How to Cite

1.
الركاد ح, راهب ا. Preparation and Characterization of solid base Cat.TS-7 from natural Syrian zeolite TS-7. TUJ-BA [Internet]. 2023Mar.27 [cited 2024Nov.24];45(1):27-35. Available from: https://journal.tishreen.edu.sy/index.php/bassnc/article/view/14104

Issue

Vol. 45 No. 1 (2023): Tishreen University Journal of Research and Scientific Studies - Basic Sciences Series

Section

Articles

License

Creative Commons License

This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.

The authors retain the copyright and grant the right to publish in the magazine for the first time with the transfer of the commercial right to the Tishreen University Journal -Basic Sciences Series  

 Under a CC BY- NC-SA 04 license that allows others to share the work with of the work's authorship and initial publication in this journal. Authors can use a copy of their articles in their scientific activity, and on their scientific websites, provided that the place of publication is indicted in Tishreen University Journal -Basic Sciences Series .  The Readers have the right to send, print and subscribe to the initial version of the article, and the title of Tishreen University Journal -Basic Sciences Series   Publisher

 

journal uses a CC BY-NC-SA license which mean

You are free to:

  • Adapt — remix, transform, and build upon the material
  •  
  • The licensor cannot revoke these freedoms as long as you follow the license terms.

 

  • Attribution — You must give appropriate credit, provide a link to the license, and indicate if changes were made. You may do so in any reasonable manner, but not in any way that suggests the licensor endorses you or your use.
  • NonCommercial — You may not use the material for commercial purposes.
  • ShareAlike — If you remix, transform, or build upon the material, you must distribute your contributions under the same license as the original.
  • No additional restrictions — You may not apply legal terms or technological measures that legally restrict others from doing anything the license permits.